Dunn nrcnmsssfst public meetingggy with nuclear energy institute on chloride induced stress corrosion cracking regulatory issue resolution protocol august 5, 2014. Nevertheless, it is recommended that where pipework or vessels develop leaks in service, they should always be investigated for possible clscc by nde non. Stress corrosion cracking of austenitic stainless steels 1011820 technical update, september 2005. Stress corrosion cracking scc is characterized by cracks propagating either transgranularly or intergranularly along grain boundaries. Three different mechanisms involved in stress corrosion. Chloride stress corrosion cracking clscc is a type of stress corrosion cracking scc and is one of the most well known forms of scc in the refining and chemical processing industries. Deterioration by clscc can lead to failures that have the potential to release stored energy andor hazardous substances. Sulfide stress corrosion cracking of steels corrosion. Chloride stress corrosion cracking stainless steel the three conditions that must be present for chloride stress corrosion to occur are as follows.
Schematic view of stress corrosion cracking scc and corrosion fatigue cracking. Stress corrosion cracking the international institute of. Duplex stainless steels, such as alloy 2205 uns s32205, resist dry chlorine but the ferrite phase is preferentially attacked by hcl should ingress of moisture occur. Chlorideinduced stress corrosion cracking of powder. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning.
Chloride stress corrosion cracking inspectioneering. The stress can be externally applied or it can be an internal residual stress. Alloy selection for service in chlorine, hydrogen chloride. Api recommended practice 574, inspection practices for piping system components 4th edition, november. At higher temperatures, stress corrosion cracking and corrosion fatigue are possible. Oct 21, 2019 stress corrosion, also known as stress corrosion cracking, is a type of corrosion that occurs due to the simultaneous action of a corrodent and a sustained tensile stress. Chlorideinduced stress corrosion cracking tests and.
Chloride stress corrosion cracking in austenitic stainless. Significant scc could affect the ability of the spent fuel storage canisters to perform their confinement function during the initial license or license renewal storage periods. Dunn nrcnmsssfst public meetingggy with nuclear energy institute on. It occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions and high temperature. Alloy 20 uns n08020 or the cast version cn7m valves. Hazards of organic chloride to petroleum processing in. Sulfide stress cracking nace mr01752002, mr0175iso. On the stress corrosion cracking and hydrogen embrittlement. Stress corrosion cracking of an austenitic stainless steel in.
Austenitic stainless steel piping is susceptible to tgscc when tensile stresses are applied in a chloride environment where local temperatures exceed approximately 140 of. Critical nominal stress and critical stress intensity factors for sulfide stress corrosion cracking of various steels were determined using fatigueprecracked, laboratory, cantilever beam specimens and short lengths of oil field casing and tubing pressured to failure. Feb 22, 2001 chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. There are several types of stress corrosion cracking scc, for example, chlorideinduced scc and h 2 sinduced scc. Effect of distance from the sea on carbon steel corrosion rates at aracaju. Pdf stress corrosion cracking of austenitic stainless.
Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Chlorideinduced stress corrosion cracking of oxidedispersionstrengthened austenitic steels xueliang yan, fei wang, lejun jiang, xiaoxing qiu, yongfeng lu, michael nastasi, zhangjian zhou, and bai cui, abstract the stress corrosion cracking scc behavior of oxidedispersionstrengthened ods 304 austenitic steels has been. Figure 5 a the copson curve for chlorideinduced scc of stainless steels. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. Case studies on chloride scc below 60c 140f, chloride scc under. This damage mechanism primarily affects standard and high carbon stainless steels, but low carbon and chemically stabilized stainless steels may also be vulnerable under certain conditions. One of the most important forms of stress corrosion that concerns the nuclear industry is chloride stress corrosion. Conclusion is made that chloride stress corrosion cracking of these steels in the temperature range of 165 f to 200 f is less severe than that experienced at 500 f and that specific conditions are required for corrosion cracking to occur at all. Explains caustic embrittlement, season cracking, hydrogen embrittlement.
Stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Stress corrosion crack an overview sciencedirect topics. Chloride stress corrosion cracking initiates from sites of localized pitting or crevice corrosion. This type of failure is known as stress corrosion cracking, often abbreviated to scc. Moat of the cracking failures have occurred at temperaturea near the boiling point. Effects of marine environments on stress corrosion. Chloride stress corrosion cracking of austenitic stainless.
Conventional stainless steels such as 304l and 316l are susceptible to chloride stress corrosion cracking ssc under certain conditions. Temperature is a significant environmental factor affecting cracking. Oct 21, 2019 chloride stress corrosion cracking cscc is a type of intergranular corrosion. While no stainless steel can be completely immune, swageloks alloy 316 stainless steel fittings have performed exceptionally well in testing. The combined action of tensile stress with corrosive environment can lead to chloride stress corrosion cracking cscc. Stress corrosion cracking of an austenitic stainless steel. Chloride oxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Jan 22, 20 stress corrosion cracking is a failure mechanism that is caused by environment, susceptible material, and tensile stress. Nov 11, 2018 this explains the stress corrosion and the conditions.
The actual pitting corrosion phenomenon is shown on propeller shaft of high speed craft, and the pit depth was measured with dial. Or a structure under static tensile stress, much below the yield stress, in contact with corrosive environment may fail due to scc. Chlorideinduced stress corrosion cracking tests and example aging management program darrell s. Stress corrosion cracking international institute of. While clearly intended to be used only for oil field equipment, industry has applied mr0175 in to many other areas including refineries, lng plants, pipelines and natural gas. Stress corrosion cracking issues in syngas plants that may be. This mechanism is characterized by corrosion in the microscopic granular composition of a metals surface.
Stress corrosion cracking scc is interpreted to take place due to specific combinations of susceptible materials in suitable corrosion environments under adequate stress, specifically under constant stress, figure 1. Standard practice for evaluating stresscorrosioncracking. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of oxygen, chloride ions, and high temperature. Increase the water injection in the highpressure air cooler 19, heat exchanger 21,24 to improve the washing efficiency of ammonium chloride. However, the growth and propagation of a crack is widely affected by. Corrosion, dealloying, stresscorrosion cracking, fracture, dislocation, cleavage. Although this test may be performed using various concentrations of magnesium chloride, this procedure covers a test solution held at a constant boiling temperature of 155. Whenever stainless steel is exposed to chloride concentrations and stress levels, chloride stress corrosion cracking cscc can occur.
Chloride ions are present in the environment dissolved oxygen is present in the environment metal is under tensile stress austenitic stainless steel is a non magnetic alloy consisting of iron. The stress corrosion cracking scc and hydrogen embrittlement he behaviors for types 304, 310, and 316 austenitic stainless steels were investigated in boiling saturated magnesium chloride solutions using a constant load method under different conditions including test temperature, applied stress, and sensitization. With a nickel content of 25%, 904l has proven to be a good alternative to most conventional stainless steels. Stress corrosion cracking of titanium preliminary report. In nace mr0175iso 15156, however, but both ssc and chloride stress corrosion cracking scc are considered. The mechanism of scc is shown as a simple representation in figure 1. Chloride induced stress corrosion cracking tests and example aging management program darrell s.
Polarization curves on titanium oxide surfaces and kinetic data for oxidation of newly formed titanium alloy surface were also obtained. Laboratory tests have shown that sandvik saf 2205 possesses good resistance to stress corrosion cracking in environments containing hydrogen sulphide. In direct contrast to ordinary chlorideinduced stress corrosion cracking, ferritic stainless steels are more sensitive to this type of stress corrosion cracking, than austenitic steels. Chloride stress corrosion cracking in austenitic stainless steel.
Stress corrosion cracking issues in syngas plants that may. Chloride stress corrosion is a type of intergranular corrosion and occurs in austenitic stainless steel under tensile stress in the presence of. Pitting corrosion of a stainless steel is illustrated in the figure 1. Chlorideinduced stress corrosion cracking tests and example. Stress corrosion cracking an overview sciencedirect topics. However, stress corrosion cracking continues to be a problem in aging plants and must be considered when completing a riskbased inspection program or setting integrity operating windows. Singh raman 1, and wai hoong siew 2 1 department of mechanical and aerospace engineering, monash university, melbourne, victoria 3800, australia 2 mechanical engineer, ibm australia 60 city road melbourne, victoria 3006 australia. Effects of marine environments on stress corrosion cracking. Chlorideinduced stress corrosion cracking of oxide. Stress corrosion cracking of titanium preliminary report on.
Where failures have been reported below the boiling point, there is a possibility that sodium chloride may have been piesent in the aolutiona and con tributed to the failures. Especially in case of chloride stress corrosion cracking, it has been shown that accumulation of chloride ions and consequent destruction of the passive film would be greater in the presence of deep grooves on the surface shoji 2003. Sulfide stress cracking nace mr01752002, mr0175iso 15156. Chloride induced cracking of stainless steels, caustic cracking of plain carbon steels, and ammonia damage to copper alloys are typical examples of this problem. Average chloride concentration mgl or ppm in rainwater in the us 2323 figure 22. The initiation of crack is more dependent on chloride concentration but less dependent on temperature. Stress corrosion, also known as stress corrosion cracking, is a type of corrosion that occurs due to the simultaneous action of a corrodent and a sustained tensile stress. Both of type 304 and type 316 stainless steels showed quite similar. Chlorideoxygen stress corrosion cracking mechanisms of austenitic chromiumnickel steels in high purity water at 250 to 350 c over a wide range of stress levels is reported. Siconversionunits inviewofpresentacceptedpracticeinthistechnologicalarea,u.
Chloride stress corrosion cracking clscc is one the most common reasons why austenitic stainless steel pipework and vessels deteriorate in the chemical processing and petrochemical industries. Stress corrosion cracking is a form of localised failure which is more severe under the combined action of stress and corrosion than would be expected from the sum of the individual effects acting alone. Stress corrosion cracking implies cracking due to combined effect of corrosion with stress. Addition of oxygen in autoclaves promoted the tendency to stress corrosion cracking.
To evaluate chlorideinduced stress corrosion cracking of type 304 stainless steel, corrosion 2012, march 1115, 2012, salt lake city, ut, agencywide documents access and management system adams accession no. Stress corrosion cracking scc is the simultaneous action of a tensile stress and an aggressive environment on an alloy system to produce a brittle fracture in a normally ductile material at stress levels far below engineering design limits. Corrosion under insulation cui is a severe problem for 304 stainless steel pressure vessel. Integral to johns manville thermo1200 and to sproule wr1200 is xox corrosion inhibitor, a distinctive formula and process that inhibits corrosion to the outside surfaces of pipe and equipment, especially. Chloride stress corrosion cracking cscc is a type of intergranular corrosion. Initiated stress corrosion cracking revised final white paper, which provides additional information on scc. The equivalent mechanism for crack growth under cyclic stresses is called corrosion fatigue cf, and crack growth here depends upon the stress ratio. This explains the stress corrosion and the conditions.
The chloride induced stress corrosion cracking scc resistance of nitrogenalloyed, powder metallurgically pm produced and hot isostatically pressed hip duplex stainless steels dss was investigated and compared to the scc resistance of two commercial wrought forged dss. A corrosive medium especially chloridebearing or hydrogensulphide h 2 s media. The problem of stress corrosion cracking scc, which causes sudden failure of metals and other materials subjected to stress in corrosive environments, has a significant impact on a number of sectors including the oil and gas industries and nuclear power production. However, high corrosion rates will occur if tantalum is used in caustic applications such as sodium hydroxide, even at room temperature. Chloride stress corrosion cracking methods of minimizing. The stress of welding part should be eliminated to prevent weld corrosion cracking 19. This study is to identify factors responsible for loss of production due to problems in plant and equipment.